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One may distinguish between "two-dimensional" LEED and "three-dimensional" LEED. In two-dimensional LEED one observes only the shape of the diffraction pattern (as seen and easily photographed on a fluorescent screen). , they are a (reciprocal) map of the surface periodicities. They therefore inform us about size and orientation of the surface unit cell: this is important information, since the presence of, for example, reconstruction-induced and overlayer-induced superlattices is made immediately visible.

At the outer edge of the outermost atoms (final-state multiple scattering of the emitted electron is however similar in SPI and photoemission). SPI has similarities with INS, but is 40 6 Method Sensitive to Electron Distribution at Surfaces intrinsically easier to interpret, mainly because of the absence of a deconvolution of the surface density of occupied states; furthermore SPI is more surface-sensitive even than INS. SPI is currently being applied to clean metal surfaces and to CO adsorbed on such surfaces.

250 . ' . I . Pd(lO v o 200 F { ~--Pd(lll) OD,Surf: 1420K± I0% { o Pd(lO0) ePd(lll} 150 0 I 300 I 200 I00 I 400 500 eV I I I I Joc Bulk Volue [I/ ,~0 ]"" " U"--u,ol ~/I OD,s~,f:37'K+-20%("01 _ ///I 8D,Surf =49°K't20%(HI) __1 -j 25 o (t~0) I 25 i I 5O 75 I IOO 25 eV Fig. 4 . 4 . Measured Debye temperatures as a function of electron kinetic energy for P d (top) and Pb (bottom) surfaces 4. 2 RHEED and MEED (Reflection High-Energy Electron Diffraction and Medium-Energy Electron Diffraction) RHEED and MEED x4) differ from LEED in the range of energies used: while in LEED "low" energies of about 10-500 eV are used, in RHEED "high" energies of about 1 - 1 0 keV are used, with MEED bridging the intermediate energy range.

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A barrier function method for minimax problems by E Polak

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